首页> 外文OA文献 >Sintesis dan Karakterisasi Biodiesel dari Minyak Kemiri Sunan (Reutealis Trisperma Oil) dengan Katalis Koh (Variasi Konsentrasi Katalis)
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Sintesis dan Karakterisasi Biodiesel dari Minyak Kemiri Sunan (Reutealis Trisperma Oil) dengan Katalis Koh (Variasi Konsentrasi Katalis)

机译:Koha催化剂从富勒木油中合成生物柴油和表征(催化剂浓度的变化)

摘要

__________________________________________________________________________________________ In this research new feedstock biodiesel was produced from Crude Reutealis Trisperma-Oil (RETRO). RETRO is vegetable oil that is overabundance in Indonesia it has not been explored because of its toxicity. RETRO was prepared through the reaction of esterification with methanol by using sulfuric acid catalyst to decrease Free Fatty Acid (FFA), and then transesterification reaction of refined RETRO was performed with methanol by using the alkaline catalyst. RETRO transesterification reaction using potassium hidroxyde (KOH) as catalyst with variation of 0.5 – 2,0 wt% of oil has been done at 65 °C. The biodiesel yield increased with the catalyst concentration increasing of 0,5-1,0 wt% and decreased when the catalys concentration of 1,5-2,0 wt%. The optimum yield of fatty acid methyl ester (FAME) was 83,33 %, it was obtained with various KOH catalyst at the oil catalyst concentration of 1,0 wt% . The characterization of RETRO biodiesel was done by comparing it with ASTM D6751-02 method, and it got the acid number of 0,55 mgKOH/g, density of 0,90 g/cm3, viscosity of 10,63 cSt at 40 °C, cetane number of 54,7 and carbon residue of 0,24%.
机译:__________________________________________________________________________________________________________在这项研究中,新的原料生物柴油是由粗制的木犀草油(RETRO)生产的。 RETRO是在印度尼西亚过量的植物油,由于其毒性而尚未被开发。通过使用硫酸催化剂与甲醇进行酯化反应以还原游离脂肪酸(FFA)来制备RETRO,然后使用碱性催化剂与甲醇进行精制RETRO的酯交换反应。在65°C的温度下,使用氢氧化钾(KOH)作为催化剂的RETRO酯基转移反应的变化为油的0.5 – 2.0 wt%。随着催化剂浓度增加0.5-1.0 wt%,生物柴油产率增加,而当催化剂浓度为1.5-2.0 wt%时,生物柴油产率降低。脂肪酸甲酯(FAME)的最佳收率为83.33%,是在油催化剂浓度为1,0 wt%的情况下使用各种KOH催化剂获得的。通过与ASTM D6751-02方法进行比较来对RETRO生物柴油进行表征,得到的酸值为0.55 mgKOH / g,密度为0.90 g / cm3,在40°C下的粘度为10.63 cSt ,十六烷值为54.7,碳残留量为0.24%。

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